The present thesis aims to get a fundamental understanding of how the molecular characteristics of a solute and solvent influence the thermophysical properties of mixtures consisting of a liquid and a dissolved gas. Due to their relevance as working fluids in chemical and energy engineering, accurate data for the viscosity, interfacial tension, and mutual diffusion coefficient are required for the efficient design and optimization of related processes. In this work, light scattering experiments, which can determine the thermophysical properties in macroscopic thermodynamic equilibrium, are combined with equilibrium molecular dynamics (EMD) simulations at temperatures up to 573 K. EMD simulations are able to predict multiple thermophysical properties by the analysis of the molecular motion in macroscopic thermodynamic equilibrium. The combination of EMD simulations with light scattering experiments allows for the validation of simulations as well as an interpretation of the results by studying the influence of molecular characteristics and the fluid structure on the thermophysical properties.<\/p>","protected":false},"excerpt":{"rendered":"
Die vorliegende Arbeit hat das Ziel, zu einem grundlegenden Verst\u00e4ndnis beizutragen, wie molekulare Eigenschaften gel\u00f6ster Stoffe und L\u00f6sungsmittel die thermophysikalischen Eigenschaften von Mischungen aus einer Fl\u00fcssigkeit und gel\u00f6stem Gas beeinflussen. Aufgrund ihrer Bedeutung als Arbeitsfluide in der Chemie- und Energietechnik sind genaue Daten zu Viskosit\u00e4t, Grenzfl\u00e4chenspannung und Diffusionskoeffizienten f\u00fcr die effiziente Auslegung und Optimierung von […]<\/p>\n","protected":false},"featured_media":3222,"comment_status":"open","ping_status":"closed","template":"","meta":{"_acf_changed":false},"product_brand":[],"product_cat":[85],"product_tag":[],"class_list":{"0":"post-3221","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-fau-studies-chemical-and-biological-engineering","7":"has-post-title","8":"has-post-date","9":"has-post-category","10":"has-post-tag","11":"has-post-comment","12":"has-post-author","13":"","15":"first","16":"instock","17":"taxable","18":"shipping-taxable","19":"purchasable","20":"product-type-simple"},"acf":{"autor":"Klein, Tobias","orcid":"0000-0003-2361-7591","ror":"00f7hpc57","herausgeber":"","orcid_hrsg":"","rorhrsg":"","bearbeiter":"","sonstige_beteiligte_personen":"","untertitel":"","zusatz":"","jahr":"2023","zeitschrift":"","serie":"","serie_name":false,"serie_band":"","serie_jahr":"","serie_titel_band":"","vortrage":"","issn":"","isbn":"","isbn13":"978-3-96147-645-9","seiten":"xiv, 111","sonstiges":"","band":1,"auflage":"","opus":"","dspace":"22882","e-isbn_pdf":"978-3-96147-646-6","doi":"https:\/\/doi.org\/10.25593\/978-3-96147-646-6","epub":"","e-isbn_epub":"","doi_epub":"","html":"","e-isbn_html":"","doi_html":"","e-isbn_reader":"","doi_reader":"","digibib":"","urn":"urn:nbn:de:bvb:29-opus4-228828","supplementary_material":"","sprache":["Englisch"],"ausgabe":"Softcover","suche":" 9783961476459 9783961476466 ","lizenz":"BY-4","bemerkung":""},"builder_content":"","_links":{"self":[{"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/product\/3221","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/comments?post=3221"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/media\/3222"}],"wp:attachment":[{"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/media?parent=3221"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/product_brand?post=3221"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/product_cat?post=3221"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/www.university-press.fau.de\/en\/wp-json\/wp\/v2\/product_tag?post=3221"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}